With over 200 sync pairs available in Pokémon Masters EX, picking the best team can be challenging, requiring strategy, synergy, and an understanding of each pair’s strengths.
Whether you’re a beginner or a veteran, this Pokémon Masters EX tier list will help you choose the most powerful sync pairs for battles.
By understanding the strengths and roles of each sync pair, you can build the best team to tackle different game modes, including Legendary Arena, Champion Stadium, Battle Villa, and Extreme Battles.
How We Rank the Best Sync Pairs

Our Pokémon Masters EX tier list evaluates sync pairs based on these key factors:
- Flexibility – Pairs that perform well across various game modes are ranked higher.
- Role Categorization – Sync pairs are divided into Damage Dealers, Supporters, and Hybrids.
- Versatility – Top-tier pairs excel in multiple content types rather than niche scenarios.
- Self-Sufficiency – The best sync pairs can perform well without relying on specific teammates.
- Potential – Pairs with high base stats, strong move sets, and synergy receive an edge in rankings.
S+ Tier – Best of the Best Sync Pairs
These sync pairs are must-haves for serious players. They dominate in almost all game modes and offer unmatched power and synergy.
- Ash & Pikachu – One of the strongest Electric-type attackers with powerful synergy and excellent burst damage.
- Red & Articuno – A balanced sync pair with both offensive and defensive skills, making them extremely adaptable.
- Marnie & Galarian Moltres – A top-tier Dark/Flying sync pair with excellent endurance and great move synergy.
- Steven & Attack Forme Deoxys – A powerhouse with incredible offensive stats, excelling in high-damage output.
- Lusamine & Ultra Necrozma – High burst damage with strong survivability, making them a dangerous force in battle.
- Hilda & Victini – Exceptional Fire-type sync pair with explosive damage output and versatility.
- Serena & Complete Forme Zygarde – A legendary sync pair that adapts to multiple roles and battle conditions.
S Tier – Excellent Sync Pairs
These sync pairs are top-tier but may require strategic setups for full potential. They are still among the best choices for competitive play.
- Falkner & Swellow – A strong support sync pair with excellent team synergy and endurance.
- Lance & Dragonite – A reliable Dragon-type attacker with high offensive stats and AoE moves.
- Red & Mega Charizard X – A fiery powerhouse with devastating damage and strong synergy.
- Cynthia & Giratina – A solid Ghost-type sync pair with great potential in PvE content.
- Leon & Charizard – One of the best Fire-type attackers in the game, offering massive damage output.
- Blue & Mega Blastoise – A defensive tank that enhances team survivability while providing strong buffs.
- Diantha & Shiny Mega Diancie – A hybrid sync pair with offensive and defensive capabilities.
A Tier – Strong & Reliable Sync Pairs
These sync pairs are powerful but not quite at the top due to minor limitations.
- Leaf & Venusaur – A hybrid sync pair with sustainability and offensive skills.
- Kris & Feraligatr – A dependable Water-type attacker with high burst damage.
- Brendan & Sceptile – A balanced sync pair with good speed and attack.
- Marnie & Grimmsnarl – A solid Dark-type sync pair with excellent synergy options.
- Leon & Eternatus – A strong sync pair that excels in different game modes.
- Giovanni & Mega Mewtwo Y – A Psychic-type attacker with consistent damage and high speed.
- Cynthia & Mega Garchomp – A top-tier Ground-type attacker that delivers powerful AoE damage.
B Tier – Good but Situational Sync Pairs
These sync pairs are viable but require specific team setups to shine.
- Selene & Decidueye – A decent Grass-type sync pair with good offensive potential.
- Cynthia & Kommo-o – A solid Dragon-type sync pair with sustainability and high damage.
- Hilda & Emboar – A Fire-type sync pair with limited versatility.
- Barry & Empoleon – A good Water-type attacker with strategic uses in certain modes.
- Erika & Vileplume – A hybrid sync pair offering both damage and support.
- Skyla & Swanna – A strong support sync pair useful in long battles.
How to Use This Tier List Effectively

- If you’re new, focus on S+ and S tier sync pairs for investment.
- For specific game modes, consider A and B tier sync pairs as alternative options.
- Keep an eye on new sync pair releases, as rankings may shift over time.
Final Thoughts
This Pokémon Masters EX tier list helps players identify the best sync pairs to invest in for 2025, ensuring strategic choices for battles and long-term success.
While tier lists are useful, your personal playstyle and strategy matter the most. The Pokémon Masters EX tier list helps you experiment, adapt, and find what works best.
Stay updated with the latest balance changes, and check out official Pokémon Masters EX updates for new sync pair releases!
FAQs
What is a sync pair in Pokémon Masters EX?
A sync pair consists of a Pokémon Trainer and their partner Pokémon, working together in battles.
How are sync pairs ranked in this tier list?
Sync pairs are ranked based on flexibility, role categorization, versatility, self-sufficiency, and potential.
Which sync pair is the best in Pokémon Masters EX?
Some of the top-tier sync pairs include Ash & Pikachu, Red & Articuno, and Lusamine & Ultra Necrozma.
Are S+ tier sync pairs necessary for winning battles?
While they are the strongest, lower-tier sync pairs can still be viable with the right strategy.
Why are some sync pairs in lower tiers despite being powerful?
Some sync pairs are ranked lower due to niche usability, requiring specific team setups.
How often does this tier list change?
Tier rankings may change with new sync pair releases and balance updates.
Should beginners focus only on S+ tier sync pairs?
Beginners should prioritize S+ and S tier sync pairs, but A and B tier can also be useful.
Where can I find the latest updates on sync pairs?
Check official Pokémon Masters EX updates or community discussions for new sync pair rankings.